Add time:07/12/2019         Source:sciencedirect.com

[±]-Deepoxy-4,5-didehydromethylenomycin A (cas 52775-76-5) methyl ester 8 and [±]-methylenomycin A methyl ester 9 are synthesized from anthracene adduct 2 via a common intermediate 13. Flash vacuum pyrolysis of adduct 13 gives 8, while stereospecific epoxidation of 13 followed by pyrolysis yields 9.

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