Add time:08/01/2019 Source:sciencedirect.com
Alkaline activated aluminosilicate materials have been studied mainly in the building industry as a substitute for concretes, ceramic materials and thermal insulations, but their properties predispose them to much greater use in the chemical industry. The aim of this study is to determine whether the alkaline activated natural zeolites can be modified to obtain a suitable chemical and textural properties for catalyst supports or sorbents. The alkaline activated natural zeolites with the clinoptilolite (cas 12173-10-3) structure were foamed using Al powder and H2O2 solution. The prepared foam pellets were post-synthetically modified by HCl leaching and analyzed to compare their properties by XRF, XRD, N2 physisorption, Hg porosimetry, DRIFT, TGA, SEM and the cutting-edge strength methods. The analysis showed that the clinoptilolite structure of the basic raw zeolite was partially preserved and porous materials had sufficient strength, a density of about 0.8 g/cm3 and a specific surface area up to 160 m2/g making them suitable as catalyst supports or sorbents.
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