A simple synthesis of the metabotropic receptor ligand (2S)-α-(hydroxymethyl)-glutamic acid and its Fmoc protected derivatives-Science-Chemical Encyclopedia-lookchem

A simple synthesis of the metabotropic receptor ligand (2S)-α-(hydroxymethyl)-glutamic acid and its Fmoc protected derivatives
Add time:08/02/2019 Source:sciencedirect.com

The highly enantioselective synthesis of (2S)-α-(hydroxymethyl)-glutamic acid 2, a potent metabotropic receptor ligand, was accomplished using the improved Schöllkopf methodology for the construction of quaternary α-amino acids and β-lactams. This was converted to a derivative suitably protected for direct use in Fmoc solid phase peptide synthesis.

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