Synthesis, spectroscopy, and structures of new rhodium(I) and rhodium(III) corroles and catalysis thereby-Science-Chemical Encyclopedia-lookchem

Synthesis, spectroscopy, and structures of new rhodium(I) and rhodium(III) corroles and catalysis thereby
Add time:08/06/2019 Source:sciencedirect.com

The syntheses and molecular structures of six- and five-coordinated rhodium(III) corroles (by pyridines and a chiral amine, respectively) and the rhodium(I) complex of a chiral corrole are described, together with some interesting features in the NMR spectra of the complexes and their utilization as carbene-transfer catalysts.

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