Add time:08/01/2019 Source:sciencedirect.com
TiO2 nanoparticles with unique crystalline-core/disordered-shell structures were synthesized in a one step process by employing 4-methoxycalix[7]arene nanoreactors. The nanoparticles were anchored on the surface of quartz beads as a monolayer and showed high visible-light driven photocatalytic activity, excellent long term durability and anti-poisoning property. Photocatalytic performance of the TiO2 nanoparticles was tested in a packed bed and complete decolorization of methyl orange was achieved under ultraviolet light or visible light. The decolorization process followed first-order kinetics and showed different behaviors for ultraviolet and visible radiation, while the overall rates of degradation were the same.
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