Sodium persulfate-promoted site-selective synthesis of mononitroarylamines under transition-metal-free conditions-Science-Chemical Encyclopedia-lookchem

Sodium persulfate-promoted site-selective synthesis of mononitroarylamines under transition-metal-free conditions
Add time:07/11/2019 Source:sciencedirect.com

A practical preparation of nitroarylamines from protected arylamines was herein disclosed. In this system, sodium nitrite acted as a nitration reagent in the presence of sodium persulfate without any transition-metal catalysts. This efficient site-selective protocol took place at room temperature for a short time through a free radical pathway.

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