Add time:08/04/2019         Source:sciencedirect.com

Transparent, thermally stable, and semiaromatic poly(amide–imide)s were prepared from hydrogenated trimellitic anhydride chloride (h-TAC) with various aromatic diamines. The dependence of thermostability on the monomer sequence and terminal group was investigated. Thermogravimetric/differential thermal analysis (TG/DTA) was performed to evaluate the thermostabilities, which were found to be primarily affected by the monomer sequence in the polymer units. The 5% weight loss temperature (Td5) in N2, glass transition temperature (Tg), and cutoff wavelength of the ultraviolet–visible (UV–Vis) spectrum (λcut) of the semiaromatic poly(amide–imide)s are 422–456 °C, 131–274 °C, and 293–321 nm, respectively, while those of wholly aromatic poly(amide–imide)s are 454–480 °C, 169–287 °C, and 415 nm, respectively.

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