Add time:08/02/2019         Source:sciencedirect.com

The natural enantiomer of the fungal metabolite (+)-palitantin (cas 15265-28-8) has been synthesized by adopting a chemoenzymatic and organocatalytic approach. Lipase catalyzed kinetic resolution, Sharpless asymmetric dihydroxylation and organocatalytic asymmetric hydroxymethylation are the key steps involved in the total synthesis of the target molecule.

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