Add time:08/02/2019         Source:sciencedirect.com

Twelve coordination compounds of Mn2+, Fe2+, Co2+, Ni2+, Cu2+ and Zn2+, with mixed organic ligands 5-methylisophthalic acid, 2,2′-bipyridine or phenanthroline, have been hydrothermally synthesised and characterised. The magnetic properties of the Mn2+, Co2+, Ni2+ and Cu2+ compounds have been investigated. Structure analysis shows that the assemblies with a bridging ligand possessing a smaller methyl group (compared to the tert-butyl group) afford coordination compounds containing multinuclear metal centres and structures of higher dimension. The result shows that the structures and properties of the metal–organic materials can be finely tuned by the substituent on the organic bridging ligands.

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