Add time:08/02/2019         Source:sciencedirect.com

Dihydro-1H-phosphole-boranes 5 and 10 were prepared from phosphine oxides 1 and 9 respectively. Reaction of borane 5 with dichlorocarbene gave dihydrophosphole-dichloromethylborane 6 and tetrahydro derivative 7a as the main products, and dichlorocyclopropane 8 as the minor component. Dichlorocarbene addition reaction of boranes 10 did not afford the corresponding phosphabicyclohexanes, but the dichloromethylborane complexes of the dihydro- and tetrahydrophospholes (11 and 7 respectively). Phosphabicyclohexaneborane 13 was synthesized from P-oxide 12 by change in the functionality. The dihydrophosphinine-boranes (16) were prepared by cyclopropane ring opening of phosphabicyclohexane 13, or by change in the functionality of P-oxide 15. Reaction of dihydrophosphinine-boranes 17 with dichlorocarbene gave traces of dihydrophosphinine-dichloromethylborane 18 instead of the phosphepine. The phosphepine-borane (20) was synthesised from oxide 19. The preparation of unsaturated phosphine-boranes was complicated by reduction side-reactions. The products were characterized by 31P, 11B, 1H and 13C NMR, as well as MS data.

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