Add time:08/02/2019         Source:sciencedirect.com

The reactions of [(arene)MCl2]2 dimers with the 1,4-bis(2-pyridine carboxamido)benzene (H2L) have been reported here with the formulations as [(arene)MCl(HL)] {where, arene = p-cymene, M = Ru (1), arene = Cp*, M = Rh (2) and Ir (3)}and [{(arene)MCl}2L] {where, arene = p-cymene, M = Ru (4), arene = Cp*, M = Rh (5) and Ir (6)}, which resulted in a series of mono- and di-nuclear neutral complexes. These complexes have been characterized by various spectral analyses. Complexes 2–6 are additionally described by the single crystal X-ray diffraction studies. Single crystal X-ray analyses of complexes showed that they are neutral in nature and vicinity around the metal is distorted octahedral. The chloride atoms and Cp* moieties are in cis orientation with respect to the ligand in the case of complex 6. Complexes 2, 3 and 5 are crystallized with the solvent dichloromethane molecule.

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