Add time:08/03/2019 Source:sciencedirect.com
Phosphoenolpyruvic acid crystals, obtained by slow concentration of an aqueous solution, are triclinic, space group P1, with a = 5.905(5), b = 8.135(8), c = 14.095(15) Å, α = 104.70(8), β = 97.72(8), γ = 100.99(8)°, and Z = 4. Two crystallographically independent phosphoenolpyruvic acid molecules differ in the orientation of the phosphate group relative to the enolpyruvate moiety. The phosphate groups have different tetrahedral distortions, and their PO(ester) bondlengths are 1.578(3) and 1.583(3) Å. All OH groups are involved in intermolecular hydrogen bonds.
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