Add time:08/05/2019         Source:sciencedirect.com

Condensation of 2-hydroxy-1-naphthaldehyde with (R)-(Ar)ethylamine yields the enantiopure Schiff bases, (R)-N-(Ar)ethyl-2-hydroxy-1-naphthaldimine (Ar = C6H5, 3-/4-MeOC6H4, 4-BrC6H4). These Schiff bases readily react with the dinuclear complex [Rh(η4-cod)(μ-O2CMe)]2 to afford the mononuclear complexes [Rh(η4-cod){(R)-N-(Ar)ethyl-2-oxo-1-naphthaldiminato-κ2N,O}] (Ar = C6H5 (I); 3-MeOC6H4 (II); 4-BrC6H4 (III)), respectively in C6H6/MeOH (5:1, v/v). The Schiff bases and complexes are characterized by IR, UV–Vis, 1H/13C NMR and mass spectrometry, polarimetry and HPLC. The polarimetric measurements show the enantiopurity of the Schiff bases as well as the complexes. The X-ray structure determination for III demonstrates that the deprotonated Schiff bases, (R)-N-(Ar)ethyl-2-oxo-1-naphthaldiminate, co-ordinate to the [Rh(η4-cod)]-fragment as a six-membered N,O-chelate ligand with distorted square planar geometry at the rhodium metal atom. Reaction of III with O2 leads to the formation of the oxidative aduct [Rh(η4-cod)(μ-O)]2 (IIIa). Compound I or [Rh(η4-cod){(S or R)-N-(phenyl)ethyl-salicylaldiminato}] were used for reduction of acetophenone with diphenylsilane into (±)-1-phenyl-ethanol, and conversions up to 93–97% have been achieved.

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