Add time:08/05/2019 Source:sciencedirect.com
The gas phase reaction of V4O10+ with propane is studied by infrared photodissociation spectroscopy combined with density functional calculations. Mass-selected V4O10+ clusters react with propane under thermalized, multiple collision conditions in a buffer gas filled ion trap at 100 K. Two main reaction paths are identified: (i) oxidative dehydrogenation forming V4O8(OH)2+ + propene and (ii) direct dissociation leading to formation of C3H7+ + V4O9OH. Formation of propene is effectively barrierless in the case that the initial H-atom is abstracted from a secondary C-atom. The present results highlight the additional structural information that can be gained from vibrational spectroscopy in comparison to a purely mass spectrometric characterization.
We also recommend Trading Suppliers and Manufacturers of Propane, 2-methyl-1-propoxy- (cas 15268-49-2). Pls Click Website Link as below: cas 15268-49-2 suppliers
About|Contact|Cas|Product Name|Molecular|Country|Encyclopedia
Message|New Cas|MSDS|Service|Advertisement|CAS DataBase|Article Data|Manufacturers | Chemical Catalog
©2008 LookChem.com,License: ICP
NO.:Zhejiang16009103
complaints:service@lookchem.com Desktop View