Add time:08/05/2019         Source:sciencedirect.com

A study was made of homopolymerization and copolymerization of allyl chloride (AC) and allyl N-phenylurethane (APU). Reaction orders were determined for monomers and an initiator in homopolymerization and copolymerization constants established: rAC = 0·25 and rAPU = 1·9. The dependence of rates of copolymerization on the composition of initial mixtures was examined. Results confirm that polar properties of substituents have a considerable effect on the reactivity of allyl compounds.

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