Add time:08/05/2019 Source:sciencedirect.com
Aziridinium mesylates stable in the reaction medium for several hours to over a week were observed in a rearrangement of dimethyl (1R,2S)-2-(N,N-dibenzylamino)-1-mesyloxyethylphosphonates substituted at C2 with Bn, i-Pr and t-Bu to the respective 1-(N,N-dibenzylamino)-2-mesyloxyethylphosphonates. Rates of formation of these aziridinium mesylates and rates of their reactions with poorly nucleophilic mesylate anion were governed by steric and electronic factors. The conformation of (2S,3S)-1,1-dibenzyl-2-(tert-butyl)-3-(dimethoxyphosphoryl)aziridinium mesylate in solution was established based on 1H and 13C NMR spectroscopic studies including a NOESY experiment.
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