Add time:08/05/2019         Source:sciencedirect.com

The reaction of the diselenide dication salt, 1,5-diselenoniabicyclo[3.3.0]octane bis(hexafluorophosphate) (1) with 1,5-diselenacyclooctane (2) gave the corresponding cation radical by single-electron transfer. The dication salt 1 was reduced upon treatment with fluorenyl-lithium, Na2S, NaBH4; it did not deprotonate. The cyclic voltammetry of 1 shows the reversible reduction peak at remarkably low reduction potential.

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