Add time:08/04/2019 Source:sciencedirect.com
The molecular structure of decamethyl cyclopentasilane has been determined in the gas phase at a nozzle temperature of 85°C. The geometrical parameters obtained from least squares refinements are: r(SiSi) = 2.358(3) Å, r(Si1bC) = 1.898(2) Å, q=0.68(4)Å, < CSiC = 110(2)°, < HCSi = 111(1)°, and t(HCSiSi) = 28(8)°. The data are consistent with a pseudorotational model and a model with the presence of both the twist and envelope forms.
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