Add time:08/06/2019 Source:sciencedirect.com
The reactions of diphosphorus tetraiodide with phenol and certain aliphatic alcohols, Grignard reagents, and amines have been investigated. Although small quantities of the expected substituted diphosphorus compounds have been detected spectrophotometrically among the products from some of the reactions, the major products are monophosphorus compounds and amorphous, highly polymerized solids related to red phosphorus and the solid phosphorus hydrides. Reaction paths resulting in the cleavage of the PP bond and ultimate polymer formation are considered.
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