Add time:08/05/2019         Source:sciencedirect.com

A number of complexes of trivalent iridium with 1:10-phenanthroline (phen) have been isolated. The complexes are of three types: (a) tris-chelated, [Ir(phen)3]X3.nH2O (X  Cl, Br, I, ClO4); (b) bis-chelated, [Ir(phen)2X2]X.nH2O (X  Cl, Br); (c) those containing a bis-chelated cation and a mono-chelated anion, [Ir(phen)2X2][Ir(phen)X4].nH2O (X  Cl, Br, I). The compounds of class (b) were obtained in cis and trans isomeric forms.

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