Add time:08/06/2019         Source:sciencedirect.com

The thermal decomposition of RbMnO4, pre-irradiated in the spent fuel facility at Harwell and in a hollow uranium slug in BEPO, has been investigated in the temperature range 195°–245°. The results for γ-irradiated RbMnO4 are similar to those for irradiated AgMnO4 and KMnO4 and the mechanism proposed for the latter is again suggested. The activation energy for the migration of point defects over the induction period is 1·59 eV. The p-t plots for pile irradiated RbMnO4 are complex, and have been explained in terms of a mechanism involving the formation of thermal and/or displacement spikes.

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