Electronic control of product formation in the rearrangement of 1,3-dithian-2-yl-arylmethanols-Science-Chemical Encyclopedia-lookchem

Electronic control of product formation in the rearrangement of 1,3-dithian-2-yl-arylmethanols
Add time:08/06/2019 Source:sciencedirect.com

1,3-Dithian-2-yl-phenylmethanols undergo efficient rearrangement to afford 2-phenyl-6,7-dihydro-5H-1,4-dithiepines. The reactions were found to show remarkable variation in products formation that is dictated by the substituents on the aryl ring.

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