Add time:08/06/2019 Source:sciencedirect.com
Equilibrium geometries, dipole moments, harmonic vibrational frequencies, and IR intensities have been calculated for a set of dinitrogen trioxide (cas 10544-73-7) conformers by ab initio calculations at the MP2 level with the 6-31G∗ and 6-311G∗ basis sets. The calculation results satisfactorily reproduce the experimental structural and vibrational spectral features of asym-N2O3 and sym-N2O3. Calculations at the same levels indicate that the trans-cis N2O3 is also a stable conformer of N2O3, and previously observed matrix IR spectral features that were not properly assigned should be attributed to the trans-cis structure of dinitrogen trioxide. However, our results show that the other two estimated conformers, Cs-N2O3 and cis-cis N2O3, are considered to be transition states.
We also recommend Trading Suppliers and Manufacturers of dinitrogen trioxide (cas 10544-73-7). Pls Click Website Link as below: cas 10544-73-7 suppliers
About|Contact|Cas|Product Name|Molecular|Country|Encyclopedia
Message|New Cas|MSDS|Service|Advertisement|CAS DataBase|Article Data|Manufacturers | Chemical Catalog
©2008 LookChem.com,License: ICP
NO.:Zhejiang16009103
complaints:service@lookchem.com Desktop View