Add time:08/11/2019         Source:sciencedirect.com

The title systems lead to the haloferrate(III) salt of the large 3,5-bis(N,N-dimethyliminium)-1,2,4-trithiolane cation. Oxidation of the iron(III) dithiocarbamates occurs stepwise through the formation of several intermediates, which are isolated and characterized. An alternative route to the oxidation of the thiuram sulfide is presented. All compounds were characterized by analyses, IR and UV spectroscopy, as well as magnetic measurements.

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