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  • Selective hydroformylation of olefins over the rhodium supported large porous metal–organic framework MIL-101
  • Add time:08/08/2019         Source:sciencedirect.com

    Highly porous and crystalline metal–organic framework MIL-101 has been synthesized and used for the preparation of rhodium supported catalyst. Acetylacetonato(1,5-cyclooctadiene)rhodium(I) has been used as catalyst precursor. The material has been characterized by XRD, XPS, SAXS, FTIR, SEM, TEM, AAS, and nitrogen adsorption. The catalytic properties of [email protected] have been investigated in the hydroformylation of olefins with different structure and chain length to the corresponding aldehydes. High conversion and selectivity to n-aldehydes have been achieved in the hydroformylation of n-alk-1-enes. The obtained results show that the rhodium species are highly dispersed and preferentially located at internal and less accessible sites at the supertetrahedral units.

    We also recommend Trading Suppliers and Manufacturers of ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I) (cas 12245-39-5). Pls Click Website Link as below: cas 12245-39-5 suppliers


    Prev:Rhodium(I)-catalysed cross-linking of polysiloxanes conducted at room temperature
    Next: Mechanistic investigation of cis and trans oxidative addition to acetylacetonato-1,5-cyclooctadieneiridium(I))

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