Add time:08/07/2019         Source:sciencedirect.com

Cu(I) complexes with 1,3-bis(diphenylphosphino)propane (dppp), 1,2-bis(diphenylphosphino)benzene (dppB) and perfluorinated carboxylates of the general formula [Cu(diphosphine)2](RCOO), R=C2F5, C4F9, C6F13, C8F17, C9F19, have been prepared and characterized with MS, IR and 1H, 31P, 13C, 19F, 63Cu NMR spectroscopy. The presence of distinct bis-chelated cations of [Cu(diphosphine)2]+ type and uncoordinated carboxylate anions has been proposed.

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