Stereoconvergent synthesis of C-9 to C-16 fragment of trienomycin based on the regioselective opening of γ-δ-poxy acrylates with Trimethylaluminium.-Science-Chemical Encyclopedia-lookchem

Stereoconvergent synthesis of C-9 to C-16 fragment of trienomycin based on the regioselective opening of γ-δ-poxy acrylates with Trimethylaluminium.
Add time:08/07/2019 Source:sciencedirect.com

The C-9 to C-16 fragment, a key intermediate for the synthesis of a 21 membered ansamycin antibiotic, Trienomycin has been synthesized, involving Sharpless asymmetric epoxidation and the key stereoselective methylation of γ-δ-epoxy acrylates by Trimethylaluminium.

We also recommend Trading Suppliers and Manufacturers of trienomycin C (cas 100662-00-8). Pls Click Website Link as below: cas 100662-00-8 suppliers

Prev:Novel models for correlation of Solubility constant and diffusivity of N2O in aqueous 1-dimethylamino-2-propanol
Next: Stereoselective synthesis of C-9 to C-14 segment, a key intermediate for the total synthesis of trienomycin and micotrienins.)

Click to view details

Health and Chemicalmore >