Add time:08/08/2019         Source:sciencedirect.com

This paper presents polarographic and voltammetric studies of the reduction of the herbicide Imazamethabenz (cas 100728-84-5) methyl (2/3-methyl-(4-isopropyl-4-methyl-5-oxo-2-imidazolin-2-yl)-p-toluate), on mercury and carbon electrodes. The electrochemical studies were performed in strongly acidic media (0.1–2.7 M H2SO4) as well as in the pH range of 1–12. The overall reduction process involves the uptake of two electrons. The results obtained in polarography show that there is the reduction of two species, related via an acid–base equilibrium, and having very close reduction potentials. The voltammetric results obtained with a glassy carbon electrode were very similar to those observed on mercury electrodes. The reducible group in the molecule is the imidazolinone ring. In strongly acidic media (pH < pKa), the reaction mechanism proposed is the reduction of the protonated herbicide by an electrochemical–chemical–electrochemical (ECE) process, being the r.d.s. the second electron transfer. At pH > pKa the neutral form of the herbicide is reduced and the second electron transfer becomes reversible or quasi-reversible. In basic media, the species reduced is the deprotonated imazamethabenz methyl and the r.d.s. is the second electron transfer.

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