Add time:08/09/2019 Source:sciencedirect.com
(E) and (Z) 4′,5′-Didehydro-5′-deoxy-5′-fluoroaristeromycin (9a and 9b) were synthesized utilizing the fluoro-Pummerer reaction . Fluoro olefin 9a was a time-dependent inhibitor of S-adenosyl-L- homocysteine hydrolase whereas 9b was a competitive inhibitor. The effects of 9a and 9b on T cell proliferation are presented.
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