Studies on ferrocene derivatives XIX. The acylation of [m]-ferrocenophanes and 1,1′-diethylferrocene and the direct conversion of the acylferrocenes to ethers and alkenes-Science-Chemical Encyclopedia-lookchem

Studies on ferrocene derivatives XIX. The acylation of [m]-ferrocenophanes and 1,1′-diethylferrocene and the direct conversion of the acylferrocenes to ethers and alkenes
Add time:08/09/2019 Source:sciencedirect.com

The Vilsmeir formylation of 1,1′-diethylferrocene, [3]- and [4]ferrocenophane has been shown to produce mainly, but not exclusively, the β-isomer and the ratio of β/α for the acetylation of [3]-ferrocenophane depends on the reagent used in the reaction. These aldehydes are directly converted to ethers by reduction with sodium borohydride in alcohol and also to alkenes via the Wittig reaction.

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