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  • The effect of point of substitution and silver based nanoparticles on the photophysical and optical nonlinearity of indium carboxyphenoxy phthalocyanine
  • Add time:08/16/2019         Source:sciencedirect.com

    Indium(III) chloride 1,8(11),15(18),22(25)-tetra-(3-carboxyphenoxy) phthalocyanine (1) and indium(III) chloride 2,9(10),16(17),23(24)-tetra–(3-carboxyphenoxy) phthalocyanine (2) were covalently linked to glutathione capped silver nanoparticles (AgNPs–GSH) and silver selenide/zinc sulfide (Ag2Se/ZnS–GSH) quantum dots via amide bond formation. The photophysical and nonlinear optical behaviour of the metallophthalocyanines and their conjugates with nanoparticles were investigated using the open aperture Z–scan technique. Complex 2 showed enhanced photophysical properties compared to 1. The conjugates revealed improved triplet state quantum yields (except for 1-AgNPs-GSH which afforded lower triplet state quantum yields in comparison to 1) and nonlinear optical activities in comparison to the Pc complexes. The synthesized complexes, nanoparticles and their conjugates could be potential nonlinear optical materials due to their good nonlinear optical activities.

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    Prev:Effects of differently shaped silver nanoparticles on the photophysics of pyridylsulfanyl-substituted phthalocyanines
    Next: Enhanced triplet state yields in aqueous media of asymmetric zinc phthalocyanines when conjugated to silver nanoflowers)

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