Add time:08/16/2019         Source:sciencedirect.com

Bis-(η4-1,5-cyclooctadiene)nickel(0) reacted with η5-C5H5Fe(CO)2Cl, η3-C5H5Fe(CO)3Cl, Mn(CO)5Cl and {Mn[P(OMe)3](CO)4}2 to form metal metal bonded coupling products. Partial reduction of Mn(CO)5Cl gave [MnCl(CO)3(THF)]2 shown to have a chlorine-bridged C2h structure by X-ray diffraction analysis. Ligand transfer also accompanied the reduction of Fe[P(OMe)3]2(CO)2Br2 and Fe(CO)4Cl2 to Fe[P(OMe)3]2(CO)3 and Fe(CO)5, respectively. Only partial reduction was observed for Ti(acac)2Cl2 and (η5-C5H5)2TiCl2 which gave [Ti(acac)2Cl]2 and (η5-C5H5)2Ti(py)Cl, respectively.

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