Add time:08/10/2019 Source:sciencedirect.com
The invention, and subsequent development of external cavity quantum cascade lasers (EC-QCLs) has allowed relatively simple access to a wide spectral region for high resolution laser spectroscopy. In this Letter, we demonstrate the application of a broadly tunable 5.3 μm EC-QCL to absorption spectroscopy on the fundamental band of deuterium bromide. The large tuning range is utilised to record spectra allowing the hyperfine coupling constants to be determined for the v = 0 and v = 1 levels of both D79Br and D81Br. We present the first measurement to our knowledge of e2Qq(v=1) for D81Br, given a value of 460.5 ± 12 MHz.
► Wide tunability of quantum cascade lasers suitable for high resolution spectroscopy. ► Linewidth of laser determined on a millisecond timescale. ► Hyperfine coupling constants determined for v = 0 and v = 1 for DBr.
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