Add time:08/10/2019 Source:sciencedirect.com
The thermodynamically most stable GeSiH4 isomer – silylgermylene (H3SiGeH(X1A′)) – and its perdeuterated counterpart were detected for the first time via infrared spectroscopy in low temperature silane (SiH4) – germane (GeH4) and D4-silane – D4-germane ices upon irradiation with energetic electrons through the ν5 and ν3 fundamentals at 860 cm−1 and at 1309 cm−1, respectively. Our kinetic studies suggest that silylgermylene is formed via decomposition of chemically activated silylgermane (H3SiGeH3) precursors.
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