Add time:08/20/2019         Source:sciencedirect.com

The reaction of N,N-Dimethylbenzylamine (cas 103-83-3) complex of palladium(II) with isocyanides led to a cleavage of halide bridges to give (o-C6H4CH2NMe2)Pd(RNC)Cl 2. On heating of 2 in THF, an intramolecular insertion of coordinated isocyanide took place to give the dimeric iminoacyl complex 3. Treatment of 2 or 3 with isocyanide gave (o-C6H4(CNR)CH2NMe2)Pd(RNC)Cl 4. The reaction of 3 or 4 with Grignard reagent or LiAlH4 led to the formation of N,N-dimethyl(o-aminoacyl)benzylamine.

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