The generation of α-trimethylsiloxy-o-quinodimethanes induced by one-electron reduction to o-acylbenzyltributylstannanes-Science-Chemical Encyclopedia-lookchem

The generation of α-trimethylsiloxy-o-quinodimethanes induced by one-electron reduction to o-acylbenzyltributylstannanes
Add time:08/11/2019 Source:sciencedirect.com

o-Tributylstannylmethyl benzaldehyde reacts with Zn in the presence of TMSCl and 2,6 lutidine at room temperature to give α-trimethylsiloxy-o-quinodimethane, which is trapped with dienophiles to afford cycloadducts in good to high yields.

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