Nickel-catalyzed reductive coupling of chlorodiphenylphosphine with aryl bromides into functionalized triarylphosphines-Science-Chemical Encyclopedia-lookchem

Nickel-catalyzed reductive coupling of Chlorodiphenylphosphine (cas 1079-66-9) with aryl bromides into functionalized triarylphosphines
Add time:08/12/2019 Source:sciencedirect.com

Functionalized triarylphosphines are obtained with good yields in a one-step reaction of an equimolar mixture of Chlorodiphenylphosphine (cas 1079-66-9) and an aromatic bromide in NMP or DMF at 110°C in the presence of zinc dust and a catalytic amount of NiBr2(bpy). A possible catalytic pathway is discussed.

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