Add time:08/13/2019         Source:sciencedirect.com

A series of commercially useful substituted pyridyl ureas have been synthesized via selenium dioxide-catalyzed reductive carbonylation of substituted nitrobenzene or substituted nitropyridine with amine as co-reagent and carbon monoxide as carbonyl reagent instead of phosgene in one-pot reaction. The recycling reusability of catalyst was also tested. It was also found that selenium dioxide-catalyzed reductive carbonylation of nitroaromatics exhibited reaction-controlled phase-transfer phenomena of the catalyst.

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