Add time:08/13/2019         Source:sciencedirect.com

Complex species involved in the spectrophotometric determination of cobalt with 4-(2-pyridylazo)resorcinol (PAR = H2R) were studied in solution and in the solid state. An anionic [Co(III)R2]- species was extracted from aqueous solution in chloroform by tetraphenylarsonium or tetraphenylphosphonium chloride. Stable tetraphenylarsonium and tetraphenylphosphonium salts of di-4-(2-pyridylazo)resorcinolo cobaltate(III) with the formula [(C6H5)4X][Co(III)R2] where X=As.P; and R=C11H7N3O22-, were isolated from the chloroform phase. The complexes were characterized by elemental analyses, visible, i.r., p.m.r., e.s.r. spectra, x-ray powder photographs, magnetic susceptibility and conductivity measurements. The spectral evidence and magnetic properties indicate a tridentate coordination of two 4-(2-pyridylazo) resorcinol dibasic anions, bonded to cobalt(III) in a symmetric arrangement with both azo groups coordinated to the cobalt atom through a single nitrogen lone pair.

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