Synthesis and crystallographic analysis of a bicyclic core related to the esperamicin/calichemicin aglycones-Science-Chemical Encyclopedia-lookchem

Synthesis and crystallographic analysis of a bicyclic core related to the esperamicin/calichemicin aglycones
Add time:08/21/2019 Source:sciencedirect.com

The synthesis and crystallographic analysis of a bicyclic core related to the esperamicin/calichemicin aglycones is reported. A key reaction involves the skeletal rearrangement of a mesylate derived from a type II Diels-Alder cycloadduct.

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