Add time:08/13/2019 Source:sciencedirect.com
The complexes [Cd2Cl4(bpytm)] (1), [CdBr2(bpytm)] (2), [Cd2Br4(bpytm)] (3) and [CdI2(bpytm)] (4) [bpytm=bis(2-pyridylthio)methane] were prepared and characterized by elemental chemical analysis, by IR, Raman and 1H and 13C NMR spectroscopy, and in the cases of 2 and 4 by X-ray diffractometry. In 2 and 4 the ligand is N,N′-bidentate, forming an eight-membered chelate ring.
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