A new stereoselective synthesis of biologically active di- and trienoic acids containing a (1Z,5Z)-diene moiety-Science-Chemical Encyclopedia-lookchem

A new stereoselective synthesis of biologically active di- and trienoic acids containing a (1Z,5Z)-diene moiety
Add time:08/15/2019 Source:sciencedirect.com

Natural (5Z,9Z)-dienoic acids and key precursors of biologically active trienoic acids were prepared in high yields and with high stereoselectivity using cross-cyclomagnesiation of terminal and oxygenated 1,2-dienes with EtMgBr in the presence of Mg metal and Cp2TiCl2 catalyst at the key step.

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