Add time:08/14/2019         Source:sciencedirect.com

Three manganese sulfate-oxalates, namely, H2pip·Mn2(SO4)2(ox)(H2O)2·2H2O (1), H3ipa⋅Mn2(SO4)(ox)2.5·H2O (2), and H3dpta⋅Mn2(SO4)2(ox)1.5(H2O)3 (3), were prepared under solvent-free conditions, where pip = piperazine, ox = oxalate, ipa = 3,3′-iminobis(N,N-dimethylpropylamine), and dpta = dipropylenetriamine. These compounds have different layered structures intercalated with organic cations. Their pore apertures range from small 8-membered ring (8 MR) to large 12 MR and extra-large 20 MR. The temperature dependence of the magnetic susceptibility of these compounds were also investigated.

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