Nature of a cation radical inγ-irradiated N-acetyl DL-methionine as disclosed from 33S-hyperfine coupling-Science-Chemical Encyclopedia-lookchem

Nature of a cation radical inγ-irradiated N-acetyl DL-methionine as disclosed from 33S-hyperfine coupling
Add time:08/16/2019 Source:sciencedirect.com

The 33S-hyperfine tensor has been determined in a radical cation of N-acetyl DL-methionine produced by γ-irradiation at 77 K. The small s-character (3.2%) indicates that the unpaired orbital consists essentially of sulfur 3p orbitals. The intensity of the 33S satellites together with the p-character (60%) suggest strongly that the radical exists as a dimer cation.

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