Further studies on vinamidinium salt amine exchange reactions, borohydride reductions, and subsequent transformations-Science-Chemical Encyclopedia-lookchem

Further studies on vinamidinium salt amine exchange reactions, borohydride reductions, and subsequent transformations
Add time:07/14/2019 Source:sciencedirect.com

Studies directed at the amine exchange reaction of vinamidinium salts followed by sodium borohydride reduction to secondary and tertiary allylic amines are described. The tertiary allylic amines were alkylated and subjected to base mediated rearrangement to yield a variety of highly functionalized tertiary homoallylic amines.

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