Add time:08/15/2019         Source:sciencedirect.com

Chlorine monofluoride reacts with tetrasulphur tetranitride to give Thiazyl chloride (cas 17178-58-4) (monomer and trimer) and thiazyl fluoride; with further ClF, NSCl reacts to form NSF then ClNSF2, and finally N2, Cl2 and SF4. The reaction NSCl/ClF to give NSF/Cl2 reverses in SO2 solvent due to removal of ClF as SO2ClF. NSF was prepared, in a new method, by passing NSCl through a column of CsF at 110°.

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