Add time:08/15/2019         Source:sciencedirect.com

The retention behaviour of primary C1–C18n-alkanols and their propanoyl, 2-chloropropanoyl and 3-chloropropanoyl derivatives was examined isothermally on SE-30 and OV-351 capillary columns. Retention increments showing the effect of methylene substitution in the alkyl chains and of monochloro substitution in the acyl chains are presented. The considerable enhancement of terminal chlorine substitution is discussed.

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