BiI3 mediated difunctionalization of α-methylstyrenes, including azidohydroxylation and azidoiodination-Science-Chemical Encyclopedia-lookchem

BiI3 mediated difunctionalization of α-METHYLSTYRENE (cas 1319-73-9)s, including azidohydroxylation and azidoiodination
Add time:08/17/2019 Source:sciencedirect.com

BiI3 mediated vicinal azidohydroxylation of α-methylstyrenes 1 with NaN3 in wet DMF affords β-azidoalcohols 4 in good yields. In dry DMF, β-azidoiodides 6 are also obtained by BiI3 mediated vicinal azidoiodination of α-methylstyrenes 1 with NaN3. This present protocol provides the bond formations of carbon-azido/carbon-hydroxy (N3─CC─OH) bond and carbon-azido/carbon-iodo (N3─CC─I) under water-controlled conditions.

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