Add time:08/17/2019 Source:sciencedirect.com
A copper-mediated oxidative pentafluoroethylthiolation of aryl boronic acids with TMSC2F5 and S8 was developed. This reaction provides a new access to various aryl pentafluoroethyl thioethers. The use of 2-fluoropyridine as the ligand and the ability to carry out the reaction at 70 °C are key features of this oxidative coupling reaction.
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