Regioselective synthesis of ceralure B1 and A, ethyl cis-(and trans-) 5-iodo-trans-2-methylcyclohexane-1-carboxylate-Science-Chemical Encyclopedia-lookchem

Regioselective synthesis of ceralure B1 and A, ethyl cis-(and trans-) 5-iodo-trans-2-methylcyclohexane-1-carboxylate
Add time:08/19/2019 Source:sciencedirect.com

Reaction of trans-2-methyl-6-oxabicyclo[3.2.1]octan-7-one with trimethylsilyl iodide, generated in situ, followed by refluxing with ethanol gives regioselectively ethyl cis-(and trans-) 5-iodo-2-methylcyclohexane-1-carboxylate, a persistent attractant for male Mediterranean fruit flies.

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